AFC Champions League title-holders Guangzhou Evergrande will begin their defence of the continental competition against Melbourne Victory.
Evergrande became the first Chinese Super League club to win the ACL when they defeated Seoul 3-3 in the final on the away-goals rule and after further strengthening their squad in the lead-up to the 2014 season, Marcello Lippi's side will be expected to challenge again this year.
While Evergrande have seen Argentine playmaker Dario Conca depart for Fluminense, the capture of Italy international Alessandro Diamanti from Bologna has made waves in global football.
Diamanti has yet to play a competitive fixture for Evergrande but the 30-year-old attacking midfielder, who has represented Italy 17 times, should take on Victory at Tianhe Stadium on Wednesday, while Lippi will also be able to call upon blistering Brazilian forward pair Elkeson and Muriqui.
Elkeson has scored 24 goals in 28 appearances since joining Evergrande in December 2012, while Muriqui was the leading goalscorer and MVP in last year's ACL.
Victory could not face a tougher opening group-stage fixture than the trip to Guangzhou with the A-League club only having qualified for Group G on February 15 when they defeated Thailand's Muangthong United 2-1 in a play-off.
Melbourne head to China after a pulsating 4-3 win over Adelaide United in the A-League, where they trailed 2-1 at half-time, scored the next three goals and then had to survive a late onslaught from the Reds, who scored with seven minutes to go to ensure a nervous finish for Victory.
In the other Group G match, South Korea's Jeonbuk Motors will host Yokohama F Marinos of Japan.
Last year's runners-up, Seoul, will begin their 2014 ACL campaign on Tuesday at home against Australian champions Central Coast Mariners in Group F, while J. League champions Sanfrecce Hiroshima will host Beijing Guoan.
Iran's Esteghlal are the only other team that made the 2013 semi-finals that are involved in this year's competition, and they will start on Tuesday against Al Shabab of Saudi Arabia in Group A.
The other clash from Group A will see Al Jazira take on Al Rayyan.
Kashiwa Reysol were the other semi-finalists in 2013 but have not qualified this year.
In Group B, Uzbekistan's Bunyodkor will travel to Al Fateh of Saudi Arabia and Qatari club El Jaish will host Foolad of Iran, while in Group C, Al Ain face Lekhwiya and Tractor Sazi are up against Al Ittihad.
K-League champions Pohang Steelers will welcome Cerezo Osaka to South Korea in Group E, while Thai Premier League title-holders Buriram United will travel to China to take on Shandong Luneng.
Two-time champions Al Hilal will host Al Ahli in Group D and Sepahan are set for a trip to Qatar to play Al Sadd, while in Group H, Western Sydney Wanderers will make their ACL debut against Ulsan and Guizhou Renhe are up against Kawasaki Frontale.
|23||A. Diamanti||65' 85'|
|Coach: M. Lippi|
for Muriqui 46'
for Gao Lin 80'
for A. Diamanti 88'
|Pasalic keen to put injury troubles behind him at Milan|
|Guardiola delighted with Sterling form|
|Rooney should retire from England duty - Shearer|
|Hazard can ´decide´ the title - Ivanovic|
|Allardyce hails ´outstanding´ Antonio|
|Belgium can make history - Henry|
|Nice president: Call Balotelli and tell him we need a striker|
|Modric would like to see out career in Madrid|
|Geromel replaces Caio in Brazil squad|
|Mustafi: Ozil convinced me to join Arsenal|
|Pardew confirms ´one or two´ more signings|
|MLS Review: Kaka brace denies NYC top spot, Timbers beat Sounders|
|Mihajlovic: I won´t waste anymore breath on Maksimovic|
|Okon named Central Coast Mariners coach|
|´Special´ Rashford will get chance - Rooney|
|Injury forces Schurrle out of Germany squad|
|Burke snubs Premier League interest to join RB Leipzig|
|Guardiola: Nasri has a future at City, if he wants it|
|Klopp confident ´all will be good´ with Sturridge|
|Emery confident PSG will bounce back|
|Athletic may strengthen squad - Valverde|
|Fabregas dismisses exit rumours, committed to Conte and Chelsea|
|De Boer encouraged as Inter´s wait continues|
|Barca ´strengthened´ by Luis Enrique´s 100th win|
|Fekir to undergo knee operation|
|Monaco 3 Paris Saint-Germain 1: Ligue 1 champions suffer early loss|
|Aguero facing possible Manchester derby ban|
|Athletic Bilbao 0 Barcelona 1: Rakitic strike extends Barca´s strong start|
|West Ham´s Antonio handed first England call-up|
|Guardiola ´so optimistic´ after Man City´s perfect start|
|Inter 1 Palermo 1: Icardi gets De Boer´s men off the mark|
|Credit Guardiola for boost in form, says Sterling|
|Manchester City 3 West Ham 1: Hosts stay perfect under Guardiola|
|Cavani won´t return to Napoli - De Laurentiis|
|Pulis puts 48-hour deadline on Berahino future|
|Zaza awaits ´new adventure´ at West Ham|
|Karanka open to transfer ´surprises´ after strong Middlesbrough start|
|Dost completes Sporting move|
|Allardyce wanted N´Zonzi for England|
|World Cup could be expanded - Infantino|
|West Brom 0 Middlesbrough 0: Booed Berahino benched for dour draw|
|Gyan´s ´destiny´ in England, Sunderland return an option|
|Zidane wanted Pogba and Madrid are weaker without him - Raiola|
|Juventus end Matuidi pursuit|
|´He´s freaking amazing!´ - Balogun hails Dortmund´s Dembele|
|Thohir thrilled as Inter confirm Joao Mario signing|
|Fabinho expects Monaco stay despite Manchester United links|
|Infantino has Blatter wine cellar removed as part of FIFA reform commitment|
|West Ham seal Zaza loan|
|Joao Mario posts heartfelt thanks to Sporting after record-breaking Inter move|
|Aguero: I´m not competing with Ibrahimovic|
|Mihajlovic: Maksimovic is dead to me|
|Risdon replaces Wright for Socceroos|
|MLS Review: DC United in goal-fest, Impact stun Toronto|
|Schmeichel to undergo surgery|
|Milik revels in ´dream´ brace as he ignores Higuain shadow|
|Rossi to join Celta Vigo|
|Ayestaran: Barcelona target Alcacer unable to compete|
|Simeone: Winless Atletico must remain calm|
|Griezmann: Atletico must improve or face relegation fight|
|Sterling ´feels the love´ at City - Guardiola|
|Stones glad he did not end up at Chelsea|
|James impact earns Zidane´s praise|
|Montella bemoans AC Milan´s indiscipline|
|Leganes 0 Atletico Madrid 0: Returning Griezmann fails to inspire turgid visitors|
|Everton fan passes away after taking ill at Goodison Park|
|Napoli 4 AC Milan 2: Milik and Callejon at the double against Montella´s nine men|
|Aubameyang eyes Lewandowski duel|
|International break timely for Hull recruitment - Phelan|
|Real Madrid 2 Celta Vigo 1: Late Kroos strike saves hosts|
|Mourinho worry over Fellaini back injury|
|Allegri marvels at ´exceptional´ Khedira|
|Mourinho promises more chances for matchwinner Rashford|
|We didn´t play our best - Tuchel|
|Rashford: Setbacks part of football|
|No hiding, Arsenal want the title - Cech|
|Hull City 0 Manchester United 1: Rashford´s late show thwarts Phelan´s battlers|
|Bamford nearing Burnley loan|
|Leicester proved they are still one of the best - Guidolin|
|Pardew stands by unsettled Zaha|
|Koeman sympathises with Hughes´ frustration|
|Lazio 0 Juventus 1: Khedira nets again as Allegri´s men prevail|
|Moyes defends Pickford after late howler|
|Conte: Hazard can still improve|
|Hughes bemoans confusion over new refereeing directives|
|Howe regrets Bournemouth caution|
|Home draw leaves Puel frustrated|
|´A goalscorer never forgets´ - Ranieri thrilled as Vardy returns to form|
|Derby sign Vydra from Watford|
|Wenger flags imminent arrival of Mustafi, Perez|
|Crystal Palace 1 Bournemouth 1: Dann late show denies Cherries|
|Southampton 1 Sunderland 1: Pickford howler costs Black Cats two points|
|Chelsea 3 Burnley 0: Hazard shines in dominant win|
|Everton 1 Stoke City 0: Joy for Koeman at Given´s expense|
|Leicester City 2 Swansea City 1: Vardy and Morgan give champions first win|
|Watford 1 Arsenal 3: Sanchez inspires Gunners´ first win of the season|
|Borussia Dortmund 2 Mainz 1: Aubameyang double seals winning start for Tuchel´s men|
|Klopp defends benching Sturridge|
|Pochettino satisfied with Liverpool draw|
|Milner: Liverpool didn´t do enough after leading|
|Lahm ready to run the hard yards for Ancelotti|
|United have the fear factor back - Shaw|
|Tottenham 1 Liverpool 1: Rose denies Klopp´s men victory|
|Donnarumma called up as Ventura turns to youth|
|´Unique, exceptional work´ - Luis Enrique hails departed Bravo|
|Luis Enrique won´t rule out Munir exit|
|Portugal´s powerhouses divide to conquer once more|
|Ter Stegen, Mascherano in Barcelona squad for Athletic clash|
|Guardiola passion infectious, says Bravo|
|Palermo confident of Balotelli deal|
|Bayern are free of Guardiola´s chains, says Scholl|
|Ronaldo: I´ll be back in no time|
|Colombia name squad for Venezuela, Brazil qualifiers|
|Pellegrini becomes Hebei China Fortune coach|
|Klopp has ´no doubt´ over Henderson´s Liverpool future|
|Lallana understands questions over Liverpool displays|
|Real Salt Lake 2 Colorado Rapids 1: Movsisyan at the double|
|Wenger insists Perez and Mustafi are not panic buys|
|Ranieri confident of Vardy resurgence|
|Atletico send Jota on loan to Porto|
|Mourinho not rushing ´super´ Mkhitaryan|
|Bayern to meet Augsburg, Dortmund face Union in DFB-Pokal second round|